| Preface to the First Edition | ix |
| Preface to the Third Edition | xi |
| To the Instructor | xiii |
| Interactive Chemical Process Principles | xv |
| Nomenclature | xvii |
| Glossary | xx |
Part 1 | Engineering Problem Analysis | 1 |
Chapter 1 | What Some Chemical Engineers Do for a Living | 3 |
Chapter 2 | Introduction to Engineering Calculations | 7 |
2.0 | Instructional Objectives | 7 |
2.1 | Units and Dimensions | 8 |
2.2 | Conversion of Units | 9 |
2.3 | Systems of Units | 10 |
2.4 | Force and Weight | 12 |
2.5 | Numerical Calculation and Estimation | 13 |
2.6 | Dimensional Homogeneity and Dimensionless Quantities | 20 |
2.7 | Process Data Representation and Analysis | 22 |
2.8 | Summary | 30 |
| Problems | 31 |
Chapter 3 | Processes and Process Variables | 42 |
3.0 | Instructional Objectives | 43 |
3.1 | Mass and Volume | 43 |
3.2 | Flow Rate | 45 |
3.3 | Chemical Composition | 47 |
3.4 | Pressure | 54 |
3.5 | Temperature | 60 |
3.6 | Summary | 63 |
| Problems | 65 |
Part 2 | Material Balances | 81 |
Chapter 4 | Fundamentals of Material Balances | 83 |
4.0 | Instructional Objectives | 83 |
4.1 | Process Classification | 84 |
4.2 | Balances | 85 |
4.3 | Material Balance Calculations | 89 |
4.4 | Balances on Multiple-Unit Processes | 104 |
4.5 | Recycle and Bypass | 110 |
4.6 | Chemical Reaction Stoichiometry | 116 |
4.7 | Balances on Reactive Processes | 125 |
4.8 | Combustion Reactions | 142 |
4.9 | Some Additional Considerations about Chemical Processes | 151 |
4.10 | Summary | 153 |
| Problems | 155 |
Chapter 5 | Single-Phase Systems | 187 |
5.0 | Instructional Objectives | 188 |
5.1 | Liquid and Solid Densities | 189 |
5.2 | Ideal Gases | 191 |
5.3 | Equations of State for Nonideal Gases | 199 |
5.4 | The Compressibility Factor Equation of State | 206 |
5.5 | Summary | 213 |
| Problems | 214 |
Chapter 6 | Multiphase Systems | 237 |
6.0 | Instructional Objectives | 239 |
6.1 | Single-Component Phase Equilibrium | 240 |
6.2 | The Gibbs Phase Rule | 247 |
6.3 | Gas-Liquid Systems: One Condensable Component | 249 |
6.4 | Multicomponent Gas-Liquid Systems | 255 |
6.5 | Solutions of Solids in Liquids | 264 |
6.6 | Equilibrium Between Two Liquid Phases | 271 |
6.7 | Adsorption on Solid Surfaces | 275 |
6.8 | Summary | 278 |
| Problems | 280 |
Part 3 | Energy Balances | 311 |
Chapter 7 | Energy and Energy Balances | 313 |
7.0 | Instructional Objectives | 314 |
7.1 | Forms of Energy: The First Law of Thermodynamics | 315 |
7.2 | Kinetic and Potential Energy | 317 |
7.3 | Energy Balances on Closed Systems | 318 |
7.4 | Energy Balances on Open Systems at Steady State | 320 |
7.5 | Tables of Thermodynamic Data | 325 |
7.6 | Energy Balance Procedures | 329 |
7.7 | Mechanical Energy Balances | 333 |
7.8 | Summary | 337 |
| Problems | 340 |
Chapter 8 | Balances on Nonreactive Processes | 357 |
8.0 | Instructional Objectives | 357 |
8.1 | Elements of Energy Balance Calculations | 358 |
8.2 | Changes in Pressure at Constant Temperature | 365 |
8.3 | Changes in Temperature | 366 |
8.4 | Phase Change Operations | 377 |
8.5 | Mixing and Solution | 395 |
8.6 | Summary | 406 |
| Problems | 409 |
Chapter 9 | Balances on Reactive Processes | 440 |
9.0 | Instructional Objectives | 441 |
9.1 | Heats of Reaction | 442 |
9.2 | Measurement and Calculation of Heats of Reaction: Hess's Law | 445 |
9.3 | Formation Reactions and Heats of Formation | 447 |
9.4 | Heats of Combustion | 448 |
9.5 | Energy Balances on Reactive Processes | 450 |
9.6 | Fuels and Combustion | 464 |
9.7 | Summary | 473 |
| Problems | 475 |
Chapter 10 | Computer-Aided Balance Calculations | 504 |
10.0 | Instructional Objectives | 504 |
10.1 | Degree-of-Freedom Analysis Revisited | 504 |
10.2 | Sequential Modular Simulation | 511 |
10.3 | Equation-Based Simulation | 522 |
10.4 | Commercial Process Simulation Packages | 533 |
10.5 | Final Considerations | 533 |
| Problems | 534 |
Chapter 11 | Balances on Transient Processes | 543 |
11.0 | Instructional Objectives | 543 |
11.1 | The General Balance Equation...Again | 544 |
11.2 | Material Balances | 548 |
11.3 | Energy Balances on Single-Phase Nonreactive Processes | 554 |
11.4 | Simultaneous Transient Balances | 560 |
11.5 | Summary | 563 |
| Problems | 564 |
Part 4 | Case Studies | 577 |
Chapter 12 | Production of Chlorinated Polyvinyl Chloride | 579 |
| PVC Chlorination Reaction Chemistry | 580 |
| Process Description | 581 |
| Problems | 584 |
Chapter 13 | Steam Reforming of Natural Gas and Subsequent Synthesis of Methanol | 591 |
| Process Description | 592 |
| Problems | 595 |
Chapter 14 | Scrubbing of Sulfur Dioxide from Power Plant Stack Gases | 607 |
| Process Description | 603 |
| Problems | 605 |
Appendix A | Computational Techniques | 607 |
A.1 | The Method of Least Squares | 607 |
A.2 | Iterative Solution of Nonlinear Algebraic Equations | 610 |
A.3 | Numerical Integration | 622 |
Appendix B | Physical Property Tables | 627 |
B.1 | Selected Physical Property Data | 628 |
B.2 | Heat Capacities | 635 |
B.3 | Vapor Pressure of Water | 638 |
B.4 | Antoine Equation Constants | 640 |
B.5 | Properties of Saturated Steam: Temperature Table | 642 |
B.6 | Properties of Saturated Steam: Pressure Table | 644 |
B.7 | Properties of Superheated Steam | 650 |
B.8 | Specific Enthalpies of Selected Gases: SI Units | 652 |
B.9 | Specific Enthalpies of Selected Gases: American Engineering Units | 652 |
B.10 | Atomic Heat Capacities for Kopp's Rule | 653 |
B.11 | Integral Heats of Solution and Mixing at 25[degree]C | 653 |
| Answers to Test Yourselves | 655 |
| Answers to Selected Problems | 665 |
| Index | 669 |